Liquefied Wood as a Partial Substitute of Melamine-urea- Formaldehyde and Urea-formaldehyde Resins
نویسندگان
چکیده
Maritime pine (Pinus pinaster) sawdust was used to produce liquefied wood by the polyhydric method with acid catalysis. The process was optimized to produce the highest amount of liquefied wood. Wood liquefied at 160oC for 90 min was used in the adhesion tests. The bond strength of veneer glued with ureaformaldehyde and melamine-urea-formaldehyde resins and several mixtures of liquefied wood with ureaformaldehyde and melamine-urea-formaldehyde wasevaluated by automated bonding evaluation system. With the increase in liquefied wood content the bond strength decreased. Nevertheless for 20% liquefied wood the reduction of internal bond strength is relatively small and still within the minimum standards required. When 70% of liquefied wood is employed there is a significant decrease in bond strength. In conclusion it is possible to use a small amount of maritime pine sawdust liquefied wood as a partial substitute of urea-formaldehyde and melamine-urea-formaldehyde resins in the particleboard production, thus decreasing the formaldehyde content.
منابع مشابه
Investigation of Low Mole Ratio UF and UMF Resins Aimed at Lowering the Formaldehyde Emission Potential of Wood Composite Boards
Urea-melamine-formaldehyde (UMF) resins with 2.5% and 5.0% melamine levels added at the beginning of the third step of the typical urea-formaldehyde (UF) synthesis procedure were synthesized with an F/(U+M) mole ratio of 1.05 and evaluated as particleboard binders to investigate the positive effects of melamine on the formaldehyde content and physical performance of boards. Resins were tested f...
متن کاملMelamine-modified urea formaldehyde resin for bonding particleboards
For the development of a cost-effective melamine-modified urea formaldehyde resin (MUF), the study evaluated the effects of reaction pH and melamine content on resin properties and bond performance of the MUF resin adhesive systems. Eight resins, each with three replicates, were prepared in a factorial experiment that included two formulation variables: two reaction pHs (i.e., 4.5 and 8.0) and ...
متن کاملLow Mole Ratio Urea–Melamine–Formaldehyde Resins Entailing Increased Methylene-Ether Group Contents and Their Formaldehyde Emission Potentials of Wood Composite Boards
A previous study of synthesizing low mole ratio urea–formaldehyde (UF) and urea–melamine–formaldehyde (UMF) resins, which included an acidic reaction step at the beginning of the typical resin synthesis procedure to obtain higher uron-type methylene–ether group contents, was repeated with the acidic reaction step extended to a higher viscosity. Compared to previous resins, the synthesized resin...
متن کاملDevelopment of melamine modified urea formaldehyde resins based on strong acidic pH catalyzed urea formaldehyde polymer
To upgrade the performance of urea-formaldehyde (UF) resin bonded particleboards, melamine modified urea-formaldehyde (MUF) resins based on strong acidic pH catalyzed UF polymers were investigated. The study was conducted in a series of two experiments: 1) formulation of MUF resins based on a UF polymer catalyzed with strong acidic pH and 2) determination of the effects of increased melamine co...
متن کاملThe Effects of Adding Melamine at Different Resin Synthesis Points of Low Mole Ratio Urea-Melamine- Formaldehyde (UMF) Resins
Low mole ratio urea-melamine-formaldehyde (UMF) resins synthesized with 2.5% and 5.0% melamine levels added at the beginning, middle, and end points of the first alkaline step of the typical urea-formaldehyde (UF) resin synthesis procedure were compared with typical UMF resins synthesized with melamine additions made at the final alkaline step. Various resin analysis, particleboard preparation,...
متن کامل